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Showing posts with label hydrogen. Show all posts
Showing posts with label hydrogen. Show all posts

Hydrogen Fuel Cell Applications

Tuesday, April 5, 2011 | | 1 comments









There are many uses for fuel cells — right now, all of the major automakers are working to commercialize a fuel cell car. Fuel cells are powering buses, boats, trains, planes, scooters, forklifts, even bicycles. There are fuel cell-powered vending machines, vacuum cleaners and highway road signs. Miniature fuel cells for cellular phones, laptop computers and portable electronics are on their way to market. Hospitals, credit card centers, police stations, and banks are all using fuel cells to provide power to their facilities. Wastewater treatment plants and landfills are using fuel cells to convert the methane gas they produce into electricity. Telecommunications companies are installing fuel cells at cell phone and radio. The possibilities are endless. 

Fuel Cell as Power Source in Remote Location

Fuel cells are very useful as power sources in remote locations, such as spacecraft, remote weather stations, large parks, rural locations, and in certain military applications. A fuel cell system running on hydrogen can be compact and lightweight, and have no major moving parts. Because fuel cells have no moving parts and do not involve combustion, in ideal conditions they can achieve up to 99.9999% reliability. This equates to around one minute of down time in a two year period.

Since electrolyzer systems do not store fuel in themselves, but rather rely on external storage units, they can be successfully applied in large-scale energy storage, rural areas being one example. In this application, batteries would have to be largely oversized to meet the storage demand, but fuel cells only need a larger storage unit (typically cheaper than an electrochemical device).

One such pilot program is operating on Stuart Island in Washington State. There the Stuart Island Energy Initiative has built a complete, closed-loop system: Solar panels power an electrolyzer which makes hydrogen. The hydrogen is stored in a 500 gallon tank at 200 PSI, and runs a Reli On fuel cell to provide full electric back-up to the off-the-grid residence.

Fuel Cell in Residential Applications

In residential applications, small fuel cell power plants could be installed for the production of both electricity and heat or hot water for the home. 

In addition to homes in developed countries, where the market may first develop, an ideal application for fuel cells is to provide power to remote residential entities that have limited or no access to primary grid power, thereby delaying, if not eliminating, the necessity of expensive, maintenance intensive transmission line installations. These applications will be more common in developing countries, where fuel cells can provide electricity in regions gradually as development warrants and allows.


Fuel Cell in Data Centers

The propagation of  Data Centers through out the U.S. and the developed world, is a sign of continued growth in the digital age and also a significant burden on grid generation and transmission capacity. The power use density for these facilities can be in excess of 100 watts per square foot resulting in very high electrical demands for a relatively small facility. These same facilities are extremely dependent on premium quality and highly reliability power.

The potential for cogeneration at these facilities is low, however the development of the Data Center Campus concept allows cogeneration to be implements beyond the confines of the Data Center in surrounding process, office, or hospitality relate buildings. The waste heat of a fuel cell can be converted to chilled air through the absopbtion chilling process, a definite need for such a data center facility.

In 1999, the First National Bank of Omaha (FNBO) - the nation's largest privately owned bank-installed a 800-kw fuel-cell system as the primary power source for its new 200,000 square foot Technology Center's critical loads. This bank is the nation's seventh largest credit card transaction processor, handling over three million transactions per day, 365 days a year. According to officials at the bank, a single one-hour blackout could cost FNBO's credit card operation as much as $6 million in lost business.
 

Fuel Cell in Transportation

There are numerous prototype or production cars and buses based on fuel cell technology being researched or manufactured by motor car manufacturers.

The GM 1966 Electrovan was the automotive industry's first attempt at an automobile powered by a hydrogen fuel cell. The Electrovan, which weighed more than twice as much as a normal van, could travel up to 70 mph for 30 seconds.

The 2001 Chrysler Natrium used its own on-board hydrogen processor. It produces hydrogen for the fuel cell by reacting sodium borohydride fuel with Borax, both of which Chrysler claimed were naturally occurring in great quantity in the United States. The hydrogen produces electric power in the fuel cell for near-silent operation and a range of 300 miles without impinging on passenger space. Chrysler also developed vehicles which separated hydrogen from gasoline in the vehicle, the purpose being to reduce emissions without relying on a nonexistent hydrogen infrastructure and to avoid large storage tanks.

In 2005 the British firm Intelligent Energy produced the first ever working hydrogen run motorcycle called the ENV (Emission Neutral Vehicle). The motorcycle holds enough fuel to run for four hours, and to travel 100 miles in an urban area, at a top speed of 50 miles per hour. In 2004 Honda developed a fuel-cell motorcycle which utilized the Honda FC Stack.

In 2007, the Revolve Eco-Rally (launched by HRH Prince of Wales) demonstrated several fuel cell vehicles on British roads for the first time, driven by celebrities and dignitaries from Brighton to London's Trafalgar Square. Fuel cell powered race vehicles, designed and built by university students from around the world, competed in the world's first hydrogen race series called the 2008 Formula Zero Championship, which began on August 22, 2008 in Rotterdam, the Netherlands.

After this first race, Greenchoice Forze from the university of Delft (The Netherlands) became leader in the competition. Other competing teams are Element One (Detroit), HerUCLAs (LA), EUPLAtecH2 (Spain), Imperial Racing Green (London) and Zero Emission Racing Team (Leuven).

In 2008, Honda released a hydrogen vehicle, the FCX Clarity. Meanwhile there exist also other examples of bikes and bicycles with a hydrogen fuel cell engine.

A few companies are conducting hydrogen fuel cell research and practical fuel cell bus trials. Daimler AG, with thirty-six experimental units powered by Ballard Power Systems fuel cells completing a successful three-year trial, in eleven cities, in January 2007. There are also fuel cell powered buses currently active or in production, such as a fleet of Thor buses with UTC Power fuel cells in California, operated by SunLine Transit Agency. The Fuel Cell Bus Club is a global cooperative effort in trial fuel cell buses.

The first Brazilian hydrogen fuel cell bus prototype began operation in São Paulo during the first semester of 2009. The hydrogen bus was manufactured in Caxias do Sul and the hydrogen fuel will be produced in São Bernardo do Campo from water through electrolysis. The program, called "Ônibus Brasileiro a Hidrogênio" (Brazilian Hydrogen Autobus), includes three additional buses.


The Type 212 submarines of the German and Italian navies use fuel cells to remain submerged for weeks without the need to surface.

 


Fuel Cell Fueling stations

The first public hydrogen refueling station was opened in Reykjavík, Iceland in April 2003. This station serves three buses built by Daimler Chrysler that are in service in the public transport net of Reykjavík. The station produces the hydrogen it needs by itself, with an electrolyzing unit (produced by Norsk Hydro), and does not need refilling: all that enters is electricity and water. Royal Dutch Shell is also a partner in the project. The station has no roof, in order to allow any leaked hydrogen to escape to the atmosphere.

The California Hydrogen Highway is an initiative by the California Governor to implement a series of hydrogen refueling stations along that state. These stations are used to refuel hydrogen vehicles such as fuel cell vehicles and hydrogen combustion vehicles. As of July 2007 California had 179 fuel cell vehicles and twenty five stations in operation, and ten more stations have been planned for assembly in California. However, there have already been three hydrogen fueling stations decommissioned.

South Carolina also has a hydrogen freeway in the works. There are currently two hydrogen fueling stations, both in Aiken and Columbia, SC. Additional stations are expected in places around South Carolina such as Charleston, Myrtle Beach, Greenville, and Florence. According to the South Carolina Hydrogen & Fuel Cell Alliance, the Columbia station has a current capacity of 120 kg a day, with future plans to develop on-site hydrogen production from electrolysis and reformation. The Aiken station has a current capacity of 80 kg. There is extensive funding for Hydrogen fuel cell research and infrastructure in South Carolina. The University of South Carolina, a founding member of the South Carolina Hydrogen & Fuel Cell Alliance, received 12.5 million dollars from the United States Department of Energy for its Future Fuels Program.

Japan also has a hydrogen highway, as part of the Japan hydrogen fuel cell project. Twelve fueling stations have been built in 11 cities in Japan. Canada, Sweden and Norway also have hydrogenhydrogen highways implemented.


Reference Books

Modern Electric, Hybrid Electric, and Fuel Cell Vehicles

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HYDROGEN FUEL CELL

Friday, June 4, 2010 | | 5 comments

There are many renewable energy sources in the world such as hydrogen, solar, wind, biomass, hydropower, and geothermal energy. Many people think that hydrogen will be the most important fuel of the future because it meets so many requirements of a good energy system. Experts agree the ideal energy system should include the characteristics listed below:
  • should rely on domestic energy sources.
  • should be able to utilize a variety of energy sources.
  • should produce few harmful pollutants and greenhouse gas emissions.
  • should be energy efficient (high energy output from the energy input).
  • should be accessible (easy to find, produce or harness).
  • should result in stable energy prices.

Hydrogen is a versatile energy carrier that can be used to power nearly every end-use energy need. The fuel cell — an energy conversion device that can efficiently capture and use the power of hydrogen — is the key to making it happen.
  • Stationary fuel cells can be used for backup power, power for remote locations, distributed power generation, and cogeneration (in which excess heat released during electricity generation is used for other applications).
  • Fuel cells can power almost any portable application that typically uses batteries, from hand-held devices to portable generators.
  • Fuel cells can also power our transportation, including personal vehicles, trucks, buses, and marine vessels, as well as provide auxiliary power to traditional transportation technologies. Hydrogen can play a particularly important role in the future by replacing the imported petroleum we currently use in our cars and trucks.

What Is A Fuel Cell

A fuel cell is a device that produces a chemical reaction between substances, generating an electric current in the process. It is an electrochemical energy conversion device. Everyone uses another electrochemical energy conversion device, i.e. a battery. A battery contains substances that produce an electric current as they react. When all of the substances have reacted, the battery is dead; it must be replaced or recharged.

With a fuel cell, the substances (in this case, hydrogen and oxygen) are stored outside of the device. As long as there is a supply of hydrogen and oxygen, the fuel cell can continue to generate an electric current, which can be used to power motors, lights, and other electrical appliances.

Why Fuel Cells?

Fuel cells directly convert the chemical energy in hydrogen to electricity, with pure water and potentially useful heat as the only byproducts.
  • Hydrogen-powered fuel cells are not only pollution-free, but also can have two to three times the efficiency of traditional combustion technologies.
  • A conventional combustion-based power plant typically generates electricity at efficiencies of 33 to 35 percent, while fuel cell systems can generate electricity at efficiencies up to 60 percent (and even higher with cogeneration).
  • The gasoline engine in a conventional car is less than 20% efficient in converting the chemical energy in gasoline into power that moves the vehicle, under normal driving conditions. Hydrogen fuel cell vehicles,which use electric motors, are much more energy efficient and use 40-60 percent of the fuel’s energy — corresponding to more than a 50% reduction in fuel consumption, compared to a conventional vehicle with a gasoline internal combustion engine. 
In addition, fuel cells operate quietly, have fewer moving parts, and are well suited to a variety of applications.

How Do Fuel Cells Work?


A single fuel cell consists of an electrolyte sandwiched between two electrodes, an anode and a cathode. Bipolar plates on either side of the cell help distribute gases and serve as current collectors.

There are many types of fuel cells, but the most important technology for transportation applications is the polymer electrolyte (or proton exchange) membrane or PEM cell. A PEM fuel cell converts hydrogen and oxygen into water, producing an electric current during the process.

In a Polymer Electrolyte Membrane (PEM) fuel cell, which is widely regarded as the most promising for light-duty transportation, hydrogen gas flows through channels to the anode, where a catalyst causes the hydrogen molecules to separate into protons and electrons.  The anode is the negative side of the fuel cell. The anode has channels to disperse the hydrogen gas over the surface of the catalyst. Hydrogen gas under pressure enters the fuel cell on the anode side and reacts with the catalyst.

The polymer electrolyte membrane (PEM) is a specially treated material that conducts positive ions (protons), but blocks electrons from flowing through the membrane.  While the protons are conducted through the membrane to the other side of the cell, the stream of negatively-charged electrons follows an external circuit to the cathode. This flow of electrons is electricity that can be used to do work, such as power a motor.

On the other side of the cell, oxygen gas, typically drawn from the outside air, flows through channels to the cathode.  The cathode is the positive side of the fuel cell. It has channels to distribute oxygen gas to the surface of the catalyst. The oxygen reacts with the catalyst and splits into two oxygen atoms. Each oxygen atom picks up two electrons from the external circuit to form an oxygen ion (that combines with two hydrogen ions (2H+) to form a water molecule (H2O). This union is an exothermic reaction, generating heat that can be used outside the fuel cell.

The power produced by a fuel cell depends on several factors, including the fuel cell type, size, temperature at which it operates, and pressure at which gases are supplied. A single fuel cell produces approximately 1 volt or less — barely enough electricity for even the smallest applications. To increase the amount of electricity generated, individual fuel cells are combined in series to form a stack. (The term “fuel cell” is often used to refer to the entire stack, as well as to the individual cell.) Depending on the application, a fuel cell stack may contain only a few or as many as hundreds of individual cells layered together. This “scalability” makes fuel cells ideal for a wide variety of applications, from laptop computers (50-100 Watts) to homes (1-5kW), vehicles (50-125 kW), and central power generation (1-200 MW or more).

What Is Hydrogen?


Hydrogen is the simplest element known to exist. An atom of hydrogen has oneproton and one electron. It is the lightest element and a gas at normaltemperature and pressure. Hydrogen is also the most abundant gas in the universe and the source of all the energy we receive from the sun. Hydrogen has the highest energy content of any common fuel by weight, but the lowest energy content by volume.

The sun is basically a giant ball of hydrogen and helium gases. In the sun.s core, the process of fusion is continually taking place. During fusion, the protons of four hydrogen atoms combine to form one helium atom with two protons and two neutrons, releasing energy as radiation.

This radiant energy is our most important energy source. It gives us light and heat and makes plants grow. It causes the wind to blow and the rain to fall. It is stored as chemical energy in fossil fuels. Most of the energy we use originally came from the sun.s radiant energy.

Hydrogen as a gas (H2), however, doesn’t exist naturally on earth. It is found only in compound form. Combined with oxygen, it is water (H2O). Combined with carbon, it forms organic compounds such as methane (CH4), coal, and petroleum. It is found in all growing things. biomass. Hydrogen is also an abundant element in the earth.s crust.


How Is Hydrogen Made?


Since hydrogen gas is not found naturally on earth, it must be manufactured. There are many ways to do this. The fact that hydrogen can be produced using so many different domestic resources is an important reason why it is a promising energy carrier. In a hydrogen economy, we will not need to rely on a single resource or technology to meet our energy needs.

Steam Reforming


Industry produces hydrogen by steam reforming, a process in which high-temperature steam separates hydrogen atoms from carbon atoms in methane (CH4), as shown below.

     CH + H2O (steam)  ---> 3H + CO
     CO + H2O (steam) ---> CO2 + H2



Today, most of the hydrogen produced by steam reforming isn.t used as fuel but in industrial processes. Steam reforming is the most cost-effective way to produce hydrogen today and accounts for about 95 percent of the hydrogen produced in the U.S. Because of its limited supply, however, we cannot rely on natural gas to provide hydrogen over the long term. Instead, we will need to produce hydrogen using other resources and technologies, such as those listed below.

Electrolysis


One way to make hydrogen is by electrolysis.splitting water into its basic elements hydrogen and oxygen. Electrolysis involves passing an electric current through water (H2O) to separate the water molecules into hydrogen (H2) and oxygen (O2) gases.

The electricity needed for electrolysis can come from a power plant, windmill, photovoltaic cell or any other electricity generator. If the electricity is produced by renewable energy or nuclear power, there is no net increase in greenhouse gases added to the atmosphere. Hydrogen produced by electrolysis is extremely pure, but it is very expensive because of equipment costs and other factors. On the other hand, water is renewable and abundant in many areas.

Technological advances to improve efficiency and reduce costs will make electrolysis a more economical way to produce hydrogen in the future.

Photoelectrochemical Production


Photoelectrolysis uses sunlight to split water into hydrogen and oxygen. A semiconductor absorbs energy from the sun and acts as an electrode to separate the water molecules.

Biomass Gasification


In biomass gasification, wood chips and agricultural wastes are super-heated until they turn into hydrogen and other gases. Biomass can also be used to provide the heat.

Photobiological Production

 Scientists have discovered that some algae and bacteria produce hydrogen under certain conditions, using sunlight as their energy source. Experiments are underway to find ways to induce these microbes to produce hydrogen efficiently.

Coal Gasification With Carbon Sequestration

 In this process, coal is gasified (turned into a gas) with oxygen under high pressure and temperature to produce hydrogen and carbon monoxide (CO). Steam (H2O) is added to the CO to produce hydrogen and carbon dioxide (H2 and CO2). The carbon dioxide is captured and sequestered (stored) to prevent its release into the atmosphere.

Nuclear Thermochemical


In this experimental process, the heat from a controlled nuclear reaction is used to decompose water into hydrogen and oxygen in a series of complex chemical reactions.

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ReferenceBooks

Fuel Cell Fundamentals


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